Applying vacuum to your resins will apply negative air pressure to the resin and the air inside of the resin (the air you generated and created during stirring) and will cause the air bubbles to expand significantly. Once the bubbles expand, the bouyancy of those bubbles also dramatically increases which allows the bubbles to float to the top and pop. This process removes the air you introduced into the resin during the mix process and any other air that may have been trapped in the resin.
Imagine 500 tiny champagne size air bubbles throughout a container of thin syrup. Those air bubbles would love to float to the top but simply do not have the bouyancy to force their way through the thick liquid to get to the top before the syrup in the case, resin, begins to cure (anywhere from 5 to 20 minutes depending on what type of system you are using ... PR or urethane). They would however eventually get there if they had overnight to slowly make their way to the top. But once the materials gel, the tiny air bubbles are stuck and typically expand a little during the exotherm of the resin curing making them even more visible. However, bubbles the size of a gum ball would float to the top fairly quickly. Therefore, vacuum is used to greatly expand the size and bouyancy of the bubbles to help them quickly float to the top of the thick resin and pop eliminating them from your material and providing you with perfectly bubble free material to cast.
Pressure on the other hand does exactly the opposite. It does not push the bubbles out of the resins. It simply crushes them so small the human eye can not see them and holds them in that size and shape until the resin cures in which the bubbles can no longer expand and become visible. This is the reason why you must keep the resin under pressure until it is hard enough to contain the bubbles in that size. If you apply pressure to the resin, it will crush the bubbles, however if you were to release the pressure prior to the resin curing, the bubbles would simply return. If the pressure forced them out of the resin, there would be no reason to leave it under pressure until it cured. You could simply pressure the resin to evacuate the bubbles and then remove it from the pressure to cure under normal conditions. But the fact that when you do this the bubbles come back is proof that they are still in the resin, just so small you can not see them. I'd love to know if you could see them with a microscope?? Hmm.
We have a video on our site demonstrating how the vacuum works. Skip the first 4 minutes and 30 seconds where we tell people how to hook up the vac pump and chamber and go directly to the 4:30 point in the video where you see Charlie tying off the rubber glove and putting it in the chamber. This will show you how much negative air pressure you are putting on the material and how the air in your resin will expand and gain bouyancy.
Looks like you'll have to cut and paste the following link/address:
http://alumilite.com/ProdDetail.cfm?Category=Equipment&Name=Vacuum Chamber
We also have a picture/text tutorial on pressure casting that can be found:
http://alumilite.com/HowTos/PressureCastingClear.cfm
(the pictures aren't the best but I think you'll get the idea)
Hope this helps you visualize the difference and affect pressure and vacuum have on your resins.
Mike
Alumilite
800 447-9344