Alumilite - easiest to turn but doesn't polish as well and is expensive. It will shine, but it lacks the "depth of shine" you get with the other 2.
Epoxy - great polish, not as easy to turn as Alumilite but not bad, costs more than Silmar 41. Has a longer curing/thickening time which can be a problem if you want a stark border between colors.
Silmar 41 (polyester resin) - cheaper than the others, polishes as good as epoxy but can be brittle. If you cast in round pvc molds the brittleness isn't much of an issue, it's rounding out square blanks where it's a problem. Not recommended for casting below 60 degrees, I prefer above 70.
Hope this helps. I've used and prefer Silmar 41 from the start, but most of the time I cast round molds. Alumilite just doesn't finish as well so I only use it if I need to cast in cold temps which is rare as I keep a lot of blanks (75+ ) on hand. I like that Silmar thickens much faster than epoxy so I can keep the colors separate but still get a good mix/swirl in 10 minutes instead of waiting an hour.
As for curing, recently I read that Alumilite takes 7 days at room temp to fully cure. I give Silmar 2 weeks minimum. Demold time isn't the same as curing time. In my experience a fully cured blank will polish to a deeper shine than one that isn't.