I have successfully used mica powder as a colorant in both Silmar 41 (a clear polyester casting resin) and Alumilite Clear (a clear urethane casting resin). I tried it once in Alumilite White (an opaque urethane casting resin) to try to add sparkle in addition to the dyes, but I couldn't see that it had any effect at all. I haven't tried clear epoxy resin myself (others here have), but I expect that mica powder would work fine there.
Polyurethane and acrylic are different plastics that are frequently and incorrectly confused with urethane, polyester, and epoxy resins. I suppose you could make blanks out of polyurethane "bar-top finish", but I haven't heard of anybody doing it. I'm not aware of any acrylic casting resins available to the hobby market.
I hope that helps,
Eric