I've "cast" using Silmar 41 (PR), Alumilite Clear, Alumilite White, Alumilite RC3 Black, and plain old CA glue.
As a woodworker, I enjoy the smell of (not all, but most) freshly milled lumber. Likewise, as a sailor, I've come to (not so much enjoy, but) appreciate the smell of polyester resin.
I've learned how to build up a thick CA finish quickly, so I do most of my tube-on "casting" with CA glue. It's just as easy and faster for me to do it that way than to wait for PR to cure.
PR is less expensive than the Alumilite resins, and depending on how you do things, does not always require pressure to cast. It does generally require good ventilation. It can take some experimentation to account for the differences that volume, pigment, catalyst, and temperature make.
Although Alumilite clear costs more, I generally prefer it to PR (when circumstances permit the choice). It gels quicker, and is easier to synchronize pouring of multiple colors with good color separation. Alumilite clear sets up more quickly too, allowing faster turnaround of molds and pressure pot. It does require pressure for bubble-free casts.
Alumilite White, and RC3 Black are quite different from the Clear. They are opaque and have a very short open time. Tinting Alumilite White can be a challenge, because the color changes while curing, but these resins produce some very interesting results, and the easiset-turning blanks I've come across.
The Alumilite resins are very sensitive to moisture and will foam up when exposed to water. They must be kept well sealed when not in use.
I hope that helps,
Eric