Personally, I think that pressure for casting polyester resin works more to keep air in solution than it does to reduce the bubble size.I t is similar to carbonization...pressure keeps the carbon dioxide dissolved in the solution and when the cap is removed the bubbles start to "fizz". The pressure just does not allow air in solution to escape and form bubbles. I know others will disagree.
Boyle's Law: At constant temperature, as the pressure on a gas increases its volume decreases at the same rate. If the pressure is increased by a factor of two then the volume decreases by a factor of 1/2. Double one and the other is cut in half. Triple one and the other is cut by 1/3. You get the idea.
According to my calculations if I place a polyester resin casting in a pressure pot at twice the normal air pressure (approx 30 psi) then the volume decreases by one half if the temperature remains constant. One would think the "size" would be cut in half but the actual size is only reduced by about 20%. The radius of the bubble used in my calculations decreased from 2 units to 1.6 units.
Granted, the bubbles in our castings are very small and a 20% reduction in size would appear to be a helpful. Another pressure doubling would reduce the size by anther 20%.
As the polyester resin cures heat is produced and the constant temperature of Boyle's law is out the door. Charles's law states as the temperature increases a gas at a constant volume will increase in pressure. Our little bubbles are not at a constant volume so I must assume the volume will increase from the temperature rise in the curing process. I will also assume that the bubbles will either float to the surface or burst as they get larger.
I am no science person so if my logic is incorrect please correct me. I know my calculations in Boyle's law are correct as long as the temp is constant. Confusing isn't it? Have fun thinking about this.
Do a good turn daily!
Don
Maybe it is time to dig out the Ideal Gas Laws and investigate just how much those pressure pots actually do compress air bubbles...
PV=nRT
But you need to add the factors for increased solubility at increased pressure and how much was already in solution.....
Ed