John, it really depends what you are casting with. I didn't see what materials you are using. From what I have read here most people are using polyester resin of one kind or another. In most cases, in the quanties that are normally purchased, this is known as pre-promoted resin which means all the chemicals need to make it cure at room temperature have all ready been add. All you have to add is MEKP. If this is what you are using, most of them have a parifin based wax which rises to the surface during the cure period to make the surface finish non-tackey. If this is the finish you are getting you should sand it before placing another coat on top. If you don't, it may stick but will be a weak point and may cause delamination at some point in the future. I hope this helps.
JJ
JJ .. (and John) I've read what you both wrote, and JJ is correct in that
some resins have the wax added to give a cured finish.
BUT...
I haven't read of anyone here using those resins. Most everything I've seen
people using here (for PR) has been laminating resins, which DO NOT
contain the waxes, this is why you'll see people asking about 'post cure'
Post curing is necessary for a laminating resin because it comes out tacky
on the top. This is perfect for pouring another layer of resin because they
will bond. Air will inhibit the cure, so the surface (touching the air) will
remain sticky. If the wax is added, this blocks the air, so the resin cures
on the surface. Or you can put it in an oven to cure the surface.
SO .. John, if you're using the PR's that we're reading about here .. such
as the Silmar 41, Cast'n Craft etc. then pour, cure and then pour again.
They will bond. If you do a 'post cure' (such as putting the cured resin
in a toaster oven so it isn't tacky anymore) then it may de-laminate.