After doing more research following my January 22 post I have found the following:
Although many of the CA accelerators are acetone based some are n-heptane based. Along with the base there are other active ingredients. Cyanoacrylate is highly reactive which is why CA glues also contain a trace of organic sulfonic acid which functions as a stabilizer. The acetone or heptane in accelerator is the evaporating agent as they have both low boiling points as well as high vapor pressures. This means that once applied, they evaporate rapidly leaving the accelerator agents behind which deactivates the stabilizer and the CA begins to polymerize. These agents usually consist of tolidine, various quinones or some type of amine.
Alkaline substances neutralize the sulfonic acid. even hydroxide ions (OH+) from water vapor can start kicking CA into polymerization. This is why why pure acetone acts as an accelerator. Because it is hygroscopic, acetone readily absorbs water from the humidity in the air. When the acetone evaporates the hydroxide ions from the water vapor are left behind to kick the CA into polymerization.
Because of the hygroscopic nature of acetone, and because the actual amount of accelerating agent required is so small, when using a pump or some kind of atomizing sprayer for acetone based accelerators, they could potentially be diluted with additional acetone without losing their effectiveness. Although the amount would vary between manufacturers and some experimentation may be required, I have read that the dilution might be as much as 4 to 1. This would certainly help with the cost.
Personally, I buy the pressurized accelerator made by the same manufacturer of the CA finishes as I have never been happy with the poor atomization provided by most pump sprayers. I have also never tried a better atomizing pump or artists air brush type of applicator which have been previously mentioned.
Regards,
Dave