Home cast Polyester Resins can be chippy. I have also found (just to add to the confusion) that different vendors resins seem to have different properties as well. The 4 I have used are Simlar 41 from US composites, it seems to be the least chippy, Tap plastics Polyester Casting Resin, and Castin' Craft's products are very similar, and Bondo's Fiberglass resin (without the fiberglass) all are somewhat chippy, but that can be dealt with by using scary sharp tools and fast speeds on the lathe.
And if your curious, the Bondo did cast just fine, but it has a funny amber color. I used it with strong opaque pigments in dark colors, it causes color shift in light colors. Why use it? It was cheap at Lowes one night I felt like experimenting.