Well, it looks like an acrylic (polymethyl methacrylate a.k.a. PMMA) blank to me. Although some people have made ribbon-style blanks out of polyester resin (PR), the results I remember seeing had much sharper edges to the ribbons. The fact that it tapped and threaded easily also suggests acrylic. PR usually is more difficult to tap and thread.
The styrene odor, however, suggests PR. Polyester resin consists of polyester macromolecules dissolved in styrene (with additives). The styrene continues to offgas even after the resin has cured. That is what gives PR its strong smell. Acrylic has a different (and usually milder) odor. Are you sure it smelled like styrene (fiberglass) and not like vinegar (acetic)?
As noted, acrylic and PR generally are both harder than urethane. That makes them easier to polish and more scratch resistant. Urethane is typically more flexible which makes it less likely to chip or shatter if dropped.
Note that Inlace Acrylester (tm) and RhinoPlastic (tm) are both made from polyester resin, not urethane nor acrylic. Their resin formulations, however, are different than Silmar 41 (which is very popular among home-casters), and the manufacturing processes may be different as well. That is why they have very different turning characteristics.
It can be difficult to know what a blank is made of, as many polyester blanks are incorrectly advertised as acrylic. I haven't checked in a long time, but RhinoPlastic (tm) used to be advertised as acrylic despite being PR. If a blank is advertised as "Acrylic Acetate" (AA), then it probably is acrylic (PMMA).
I hope that helps,
Eric